ASP.NET

I have a gridview with a checkbox column, i select a checkbox in a row and click edit button after that, edit button click_event i wrote this:
 
grvWorkDetail.DataKeys[grvWorkDetail.SelectedIndex].Values["WorkTimeID"].ToString()
 
but it has error, and i cant access to "WorkTimeID"
 
my codebehind is :
 
<asp:TemplateField ItemStyle-VerticalAlign="Middle" ItemStyle-HorizontalAlign="Center">
                                                            <HeaderTemplate>
                                                                <asp:CheckBox ID="chk_SelectAll" runat="server" />
                                                            </HeaderTemplate>
                                                            <ItemTemplate>
                                                                <asp:CheckBox ID="chk_Select" runat="server" />
                                                            </ItemTemplate>
                                                        </asp:TemplateField>
                                    <asp:TemplateField ItemStyle-HorizontalAlign="Center"