The Process Class has properties that you can set. Review documentation to see if you want to set any of them.
Imports System.Diagnostics
Dim myProcess As New Process
Try
myProcess.StartInfo.FileName = Environment.GetFolderPath( _
Environment.SpecialFolder.System) & _
"\cmd.exe"
myProcess.Start()
Catch ex As Exception
MsgBox(String.Concat(ex.Message, vbNewLine, vbNewLine, _
"Unable to Start: cmd.exe"), _
MsgBoxStyle.Critical, "Starting CMD.EXE")
End Try