So write down sample data for each table, and establish what the relationships are.
For example, if you have an Invoices table and a InvoiceItems table:
Invoices:
Id Date Customer
1 2016-11-01 JS bits
2 2016-11-02 JS Bits
3 2016-11-03 Mikes parts
InvoiceItems:
Id InvoiceId Item
1 1 A bit
2 1 A bigger bit
3 1 A tiny bit
4 2 A tiny bit
5 3 A Part
6 3 B Part
Then it's obvious you have a one-to-many relations ship between the two tables, with InvoiceId being a Foreign key to Invoices.Id
Work out what relationships you need, and establish them in SSMS via "Database Diagrams" branch of the database in the Object Explorer pane.