Store your miles and gallons only: and store them as integers - that's what the user inputs them as.
So you need four variables: tripMiles, tripGallons, totalMiles, totalGallons.
Each time the user enters trip values, print the MPG from them:
cout << "MPG this tankful is: " << (float) tripMiles / (float(tripGallons) << endl;
And add the trip values to the totals. Output the total MPG in a similar way:
cout << "Total MPG: " << (float) totalMiles / (float(totalGallons) << endl;
Other than that, you need to re-read the miles each time round the loop, not just outside it.