try changing this line:
private OdbcConnection con = new OdbcConnection();
to this:
private OleDbConnection con = new OleDbConnection();
and you can call your mdb file like this in your app.config:
<connectionStrings>
<add name="myconn" connectionString="Provider=Microsoft.Jet.OLEDB.4.0; Data Source={0}App_Data\mydb.mdb" providerName="System.Data.OleDb"/>
</connectionStrings>
hope it helps :)