You can do it with some complicated code using
[DllImport("winmm.dll")]
public static extern int mixerGetControlDetails(IntPtr hmxobj,ref MIXERCONTROLDETAILS pmxcd, MIXER_GETCONTROLDETAILSFLAG fdwDetailsmixer);
Best option is to get the WaveLibMixer code by Gustavo Franco, e.g. from
http://volumehotkey.googlecode.com/svn-history/r2/trunk/WaveLibMixer/[
^]