Please check you app config file, should be as below
<?xml version="1.0" encoding="utf-8" ?>
<configuration>
<appSettings>
<add key="aspnet:UseTaskFriendlySynchronizationContext" value="true" />
</appSettings>
<system.web>
<compilation debug="true" />
</system.web>
<!-- When deploying the service library project, the content of the config file must be added to the host's
app.config file. System.Configuration does not support config files for libraries. -->
<system.serviceModel>
<services>
<service behaviorConfiguration="WcfServiceLibrary1.Service1Behavior"
name="WcfServiceLibrary1.Service1">
<endpoint address="" binding="netTcpBinding" bindingConfiguration=""
contract="WcfServiceLibrary1.IService1">
<identity>
<dns value="localhost" />
</identity>
</endpoint>
<endpoint address="mex" binding="mexTcpBinding" bindingConfiguration=""
contract="IMetadataExchange" />
<host>
<baseAddresses>
<add baseAddress="net.tcp://localhost:8733/Service1" />
</baseAddresses>
</host>
</service>
</services>
<behaviors>
<serviceBehaviors>
<behavior name="WcfServiceLibrary1.Service1Behavior">
<serviceMetadata httpGetEnabled="false" httpsGetEnabled="false" />
<serviceDebug includeExceptionDetailInFaults="false" />
</behavior>
</serviceBehaviors>
</behaviors>
</system.serviceModel>
</configuration>