Use the following xsl to strip off multiple namespaces:
="1.0"="utf-8"
<xsl:stylesheet version="1.0" xmlns:xsl="http://www.w3.org/1999/XSL/Transform">
<xsl:output method="xml" indent="no" />
<xsl:template match="/|comment()|processing-instruction()">
<xsl:copy>
<xsl:apply-templates />
</xsl:copy>
</xsl:template>
<xsl:template match="*">
<xsl:element name="{local-name()}">
<xsl:apply-templates select="@*|node()" />
</xsl:element>
</xsl:template>
<xsl:template match="@*">
<xsl:attribute name="{local-name()}">
<xsl:value-of select="." />
</xsl:attribute>
</xsl:template>
</xsl:stylesheet>
You can use XslCompiledTransform to transform your xml file, then use it for validation. Also remember to create xsd without multiple namespaces.