Thank you for your question. You can follow the bellow code.
DECLARE @FormatedDateTime varchar(36)
DECLARE @YourDate char(10)
DECLARE @YourTime char(10)
SELECT @YourDate = '101114'
SELECT @YourTime = '162941'
SELECT @FormatedDateTime = convert(varchar, convert(datetime, @YourDate), 111)
+ ' ' + substring(@YourTime, 1, 2)
+ ':' + substring(@YourTime, 3, 2)
+ ':' + substring(@YourTime, 5, 2)
SELECT FormattedDateTime = @FormatedDateTime
Thanks,
Mamun