Try this one exactly
"/Table/Record[TXN_CODE='MRV' and DOC_NO = '1002']"
if this doesn't work, remove the quotes for 1002 & check.
If it still does not work, try this. This may not be right
"/Table/Record[TXN_CODE='MRV'] | /Table/Record[DOC_NO = 1002]"
I think this will select all elements with TXN_CODE='MRV' AND DOC_NO=1002