Its not possible with the facebook C# API. As long as your application has the access token to the facebook and facebook responds to the requests with this access token, the user is logged into the facebook.
The alternative way is using javascript
<div id="fb-root">
<script type="text/javascript" language="javascript">
window.onload=function()
{
FB.init({ apiKey: 'b65c1efa72f570xxxxxxxxxxxxxxxxx' });
FB.getLoginStatus(handleSessionResponse);
}
function handleSessionResponse(response) {
if (!response.session) {
window.location = "/mysite/Login.aspx";
return;
}
}
</script>
</div>
More info here
http://facebooksdk.blogspot.com/2011/06/facebook-logout.html