try somethin like this.
before binding get distinct records from the table and bind it to gridview.
cmbSectionName.DataSource=datatable1.AsEnumerable()
.Select(row => row.Field<string>("Section_Name"))
.Distinct()
.ToList();
cmbSectionName.DisplayMemberPath="Section_Name";
cmbSectionName.ValueMemberPath="Section_Name";
cmbSectionName.DataBind();