The answer is obvious: your xml structure is invalid!
Proper xml should looks like:
<clients>
<client>
<name>x</name>
<surname>y</surname>
<orders>
<order>
<orderno>QA122</orderno>
</order>
<order>
<orderno>QA125</orderno>
</order>
</orders>
</client>
</clients>
or:
<clients>
<client name="x" surname="y">
<orders>
<order orderno="QA122" />
<order orderno="QA125" />
</orders>
</client>
</clients>
Depending on that, a set of classes have to be created. Then you'll be able to serialize/deserialize data.
For further details, please see:
Introducing XML Serialization | Microsoft Docs[
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XmlSerializer Class (System.Xml.Serialization) | Microsoft Docs[
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XML Serialization and Deserialization: Part 1[
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