Create a MailMessage and a SmtpClient and send it.
MailMessage msg = new MailMessage();
msg.From = new MailAddress("from@gmail.com", "Display name");
msg.Subject = "Hello mail!";
msg.Body ="This is my email";
SmtpClient client = new SmtpClient();
client.Send(msg);
You could configure you're smtp-client in app.config file.
<system.net>
<mailsettings>
<smtp from="from@gmail.com">
<network host="smtp.mail.com" port="587" username="from@mail.com" password="***" />
</smtp>
</mailsettings>
</system.net>