If you are using entity framework means you no need to write DTO again, instead you can use your entity class.
try this
in your PIAService class
List <dataaccountdatamodel> DAdetails = (from p in piaData.DataAccounts
where p.PatientAccountNumber == patientAccountNumber &&
p.Duplicate == false
select new dataaccountdatamodel{ AAA = p.aaa,BBB=p.bbb}.tolist<dataaccountdatamodel>());</dataaccountdatamodel>
add this in your interface IPIAService
[OperationContract]
List <dataaccountdatamodel> GetDetailsUsingPatientaccountNumber(string patientAccountNumber);