First, know that CodeProject is always your friend: just search in Google using:
site: codeproject.com
To find several useful articles.
There are several libraries that will wrap the VLC Control so you can use it in .NET; for example: [
^], [
^], [
^]. Two part series: [
^], [
^].
If I were going to use one of these libraries, I'd review all of them, looking to see which one is updated most recently, which one shows the author(s) responding to user feedback most recently, and which one seems like one you could work with.