Use Query
With CTE(stud_name,BatchID,Cid) as
(
select a.stud_name,
BatchID = (select eid from BATCHID where bid = 'B10458' and b_activ = 'A'),
Cid = (select top 1 certificate_no from certificate_detail where stud_id = a.stud_id and active = 'A' and crsname = 'RPSCRB')
from student a, course_registration b, batch_course_registration c where
a.stud_id=b.stud_id and b.cr_bill_no=c.cr_bill_no
and c.bcr_batch_id= 'B10458'
and b.cr_active='A' and a.stud_active<>'D')
select stud_name,BatchID,Cid, BatchID+'/'+ Cid as result from CTE
If your column BatchID and Cid are not of nvarchar type the cast it to nvarchar like
Cast(BatchID as nvarchar)+'/'+Cast(Cid as nvarchar) as result