The following is the method to bind the combo box with a datatable and the values in the datatable are from the database.
Dim sqlCon As New SqlConnection("server=yourserver;database=yourdeaabase;uid=sa;password=xxxx;")
Dim sqlDataAdapter As New SqlDataAdapter("select * from cState", sqlCon)
Dim dt As New DataTable()
sqlDataAdapter.Fill(dt)
ComboBox1.DataSource = dt
ComboBox1.DisplayMember = "StateName"
ComboBox1.ValueMember = "StateId"
The following code is without using any database tables
Dim dt As New DataTable()
dt.Columns.Add("Id")
dt.Columns.Add("Value")
Dim i As Integer
For i = 1 To 10
Dim dr As DataRow = dt.NewRow()
dr.Item(0) = i.ToString()
dr.Item(1) = i.ToString()
dt.Rows.Add(dr)
Next
ComboBox1.DataSource = dt
ComboBox1.DisplayMember = "Value"
ComboBox1.ValueMember = "Id"