Here is a sample iTextSharp pdf create program.
You must download iTextSharp from SourceForge or other site.
using iTextSharp.text;
using iTextSharp.text.html.simpleparser;
using iTextSharp.text.pdf;
using System.Web.UI.HtmlControls;
...
protected void Button1_Click(Object sender,System.EventArgs e)
{
Response.ContentType = "application/pdf";
Response.AddHeader("content-disposition", "attachment;filename=this.pdf");
Response.Cache.SetCacheability(HttpCacheability.NoCache);
StringWriter sw = new StringWriter();
HtmlTextWriter hw = new HtmlTextWriter(sw);
HtmlForm frm = new HtmlForm();
GridView1.AllowPaging = false;
GridView1.Parent.Controls.Add(frm);
frm.Controls.Add(GridView1);
frm.RenderControl(hw);
StringReader sr = new StringReader(sw.ToString());
Document PDFdoc = new Document(PageSize.A4, 10.0F, 10.0F, 10.0F, 0.0F);
iTextSharp.text.html.simpleparser.HTMLWorker htmlparser = new iTextSharp.text.html.simpleparser.HTMLWorker(PDFdoc);
PdfWriter.GetInstance(PDFdoc, Response.OutputStream);
PDFdoc.Open();
htmlparser.Parse(sr);
PDFdoc.Close();
Response.Write(PDFdoc);
Response.End();
}