You have created a variable called
$isSel
and assign it the value of "selected" if the post value matches the "emailAdd" from the rowset, but it is NOT used anywhere after its creation and assignment.
It should be:
if($row['EmailAdd'] == $_POST['UserName'])
{
$isSel = " selected";
}
else
{
$isSel = "";
}
echo "<option value='".$row['EmailAdd']."'".$isSel.">".$row['EmailAdd']."</option>";