This problem is NP-hard. Hundred vertices is enough to make any implementation run almost forever (until it runs out of memory) because it needs to compute way too many things.
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| \*/ \*/ \*/ \*/ \*/ \*/ \*/ \*/ \*/ \*/ \*/ \*/<br />
The number of simple paths in the 40-vertex graph above is 3^13, or 1,594,323. With 100 vertices it has a potential of going into trillions!
P.S. Why do you need all paths, anyway?