I have done this by doing followong method:
private void btnSnap_Click(object sender, EventArgs e)
{
pictureBox1.Image = pictureBox2.Image;
if (FinalVideo.IsRunning)
{
FinalVideo.Stop();
}
}
//where pictureBox1 is for webcam
//and
// pictureBox2 is for the snaping the the picture from pictureBox1.