I'm not sure i understand you well... But, if you would like to get unique data, you can use
Distinct() method[
^]:
var bikeSizes = xdoc.Descendants("BikeType")
.Where(x => x.Element("TypeName").Value == biketype)
.SelectMany(x => x.Descendants("SizeName").Select(y => y.Value))
.Distinct()
.ToList();