You do not want to call the SP as you may affect some data in the DB.
Instead:
SELECT * FROM sys.dm_exec_describe_first_result_set ('owner.sprocName', NULL, 0) ;
This returns the result set:
is_hidden
column_ordinal
name
is_nullable
system_type_id
system_type_name
max_length
precision
scale
collation_name
user_type_id
user_type_database
user_type_schema
user_type_name
assembly_qualified_type_name
xml_collection_id
xml_collection_database
xml_collection_schema
xml_collection_name
is_xml_document
is_case_sensitive
is_fixed_length_clr_type
source_server
source_database
source_schema
source_table
source_column
is_identity_column
is_part_of_unique_key
is_updateable
is_computed_column
is_sparse_column_set
ordinal_in_order_by_list
order_by_is_descending
order_by_list_length
error_number
error_severity
error_state
error_message
error_type
error_type_desc