use a field validator and write a regular expression (regex) to solve your problem.
here is link for regex class of .net
http://msdn.microsoft.com/en-us/library/system.text.regularexpressions.regex.aspx[
^]
and your patren would be something like this
string pattern = @"[A-Za-z][A-Za-z]\s[0-9]{6}";
[]=single occurrence from this set
\s= white space
{X}=total length is X (dont use this if the digits after space can vary).