Is your problem that it doesn't show all the Sql Servers or that you don't know how to bind the datatable to a combobox?
If it is the first;
You need to have
SQL Server Browser[
^] runing on all the computers with Sql Server on them, and you need port 1434 open on those computers.
For the second;
comboBox1.DataSource = table;
comboBox1.ValueMember = "ServerName";
comboBox1.DisplayMember = "ServerName";