Not sure where you are going with this but
char Number[8] = "6*4-4/5";
IS LITERALLY THE ANSWER .... THERE IS NOTHING TO DO
YOU ASKED A QUESTION YOU ACTUALLY GAVE THE ANSWER TOO.
Look at Number under the debugger and you will see this
Number[0] = '6';
Number[1] = '*';
Number[2] = '4';
Number[3] = '-';
Number[4] = '4';
Number[5] = '/';
Number[6] = '5';
Number[7] = 0;
All you need to do is make a string evaluate function ... you know like
bool evaluate(const char *expression, int &result)
{
...
}
Take that string and strip it and evaluate it character by character. I will even give you a hint if the number is bigger than 1 character you have to do the number bit as two stages find start and find end.
If you google it there will be thousands of things on evaluating a string sequence because it is part of any computer programming coarse.
I suspect this is homework which is why I wont fill the function in for you.