The fastest way to do this is to change your query. For example
SELECT EmployeeID,
EmployeeName,
EmployeeAddress,
0 as EmployeeSalary
FROM Employee
Doing this will automatically populate the new Column EmployeeSalary with a value of 0 which you can manipulate at run time.
If you dont want to change SQL then you can also do like this
DataColumn salaryCol = DataTable.Columns.Add("EmployeeSalary", typeof(Int32));
salaryCol.AllowDBNull = false;