Not sure what your goal is, but perhaps something like this:
int i;
char str[100][100];
for (i=0;i<100;i++)
{
for(int j=0; j<100; j++)
{
cin >> str[i][j];
}
}
Note, that's just untested pseudocode. But note how I've used 2 indices there.
[Update]
--------
His alternate thread where he described it with more details (the key point about strings vs chars) has been answered here:
list of strings in an 2d array[
^]