I will like to advise to set username as DataKey of Gridview
and do coding something like it.
protected void _rowdeleting(object sender, GridViewDeleteEventArgs e)
{
string username= GrdView1.DataKeys[e.RowIndex].Value.ToString();
MAconn.Open();
SqlCommand cmd = new SqlCommand("Delete From ROLES (UserId,GroupId) SELECT UserId FROM Users WHERE username= @username", MAconn);
cmd .Parameters.AddWithValue("@username",username);
cmd.ExecuteNonQuery();
MAconn.Close();
bind();
}