use template column in grid
and have a regular experssion like below
<asp:RegularExpressionValidator ID="REVtxtDecimal" runat="server"
ControlToValidate="txtDecimal" ErrorMessage="decimal Value-Enter only numerics.Format like (x.xx)"
Text="*" ValidationExpression="^\d+(\.\d\d)?$" Width="1px"></asp:RegularExpressionValidator>