change your bound field to <asp:templatefield xmlns:asp="#unknown"> and label in item template.after that try this on your cs page...
foreach (GridViewRow gr in Gridview1.Rows)
{
CheckBox chk = (CheckBox)gr.FindControl("CheckBox1");
if (chk.Checked == true)
{
Label lbl = (Label)gr.FindControl("label1");
}
}</asp:templatefield>