While you can not get a mouse click event directly from the browser control, you can handle various events from the HtmlDocument currently displayed in the browser to get this information.
Public Class Form1
Dim WithEvents doc As HtmlDocument
Private Sub WebBrowser1_DocumentCompleted(ByVal sender As System.Object, ByVal e As System.Windows.Forms.WebBrowserDocumentCompletedEventArgs) Handles WebBrowser1.DocumentCompleted
If WebBrowser1.Url.Equals(e.Url) Then
doc = WebBrowser1.Document
End If
End Sub
Private Sub doc_Click(ByVal sender As Object, ByVal e As System.Windows.Forms.HtmlElementEventArgs) Handles doc.Click
Debug.WriteLine(e.MousePosition)
Debug.WriteLine(e.ClientMousePosition)
End Sub
End Class