Use the InstalledVoices options. See
here
To perform text-to-speech using the language specified in the Culture property, a speech synthesis engine that supports that language-country code must be installed. The speech synthesis engines that shipped with Microsoft Windows 7 work with the following language-country codes:
en-US. English (United States)
zh-CN. Chinese (China)
zh-TW. Chinese (Taiwan)
Two-letter language codes such as "en" are also permitted.