try this
private void btnAdd_Click(object sender, EventArgs e)
{
dataGridView1.Columns.Clear();
dataGridView1.Columns.Add("EName", "Name");
dataGridView1.Columns.Add("Addr", "Addr");
dataGridView1.Columns.Add("Hno", "H-No");
DataGridViewCheckBoxColumn dgvCmb = new DataGridViewCheckBoxColumn();
dgvCmb.ValueType = typeof(bool);
dgvCmb.Name = "Column Name";
dgvCmb.HeaderText = "CheckBox";
dataGridView1.Columns.Add(dgvCmb);
}