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GeneralRe: Grumpy old git Pin
Gary R. Wheeler24-Dec-13 2:25
Gary R. Wheeler24-Dec-13 2:25 
GeneralCO2 and Antarctica Pin
Ernst Iliov Stavro Blofeld23-Dec-13 6:22
Ernst Iliov Stavro Blofeld23-Dec-13 6:22 
GeneralRe: CO2 and Antarctica Pin
harold aptroot23-Dec-13 6:43
harold aptroot23-Dec-13 6:43 
GeneralRe: CO2 and Antarctica Pin
pt140123-Dec-13 7:00
pt140123-Dec-13 7:00 
GeneralRe: CO2 and Antarctica Pin
W Balboos, GHB23-Dec-13 7:26
W Balboos, GHB23-Dec-13 7:26 
GeneralRe: CO2 and Antarctica Pin
pt140123-Dec-13 9:09
pt140123-Dec-13 9:09 
GeneralRe: CO2 and Antarctica Pin
Gregory Gadow23-Dec-13 7:59
Gregory Gadow23-Dec-13 7:59 
GeneralRe: CO2 and Antarctica Pin
W Balboos, GHB23-Dec-13 8:23
W Balboos, GHB23-Dec-13 8:23 
Gregory.Gadow wrote:
The concentration of CO2 in the air is less than the concentration of H2O, so carbon dioxide cannot freeze out, either.


No - it's an effect of a substance's partial pressure at a given temperature (vs. the solid/liquid states with which it is in contact). The materials attempt to create an equilibrium which is the appropriate partial pressure for a given conditions in contact with the solid/liquid source. IF there's not enough of the solid/liquid available to reach the equilibrium state then it all goes into the gaseous state.

An example of partial pressure would be smell of alcohol when you open a bottle: it's boiling point is above room temperature. It has a significant partial pressure and thus alcohol molecules leave the liquid phase and become a vapor above the liquid. If the bottle's closed - it stops pretty quickly. If the bottle's open, it never reaches equilibrium and so all the alcohol evaporates. The partial pressure of a solution (example, alcohol + water) is equal to the partial pressures of each component weighted by its relative molal volume. 100pf thus has a tad more than half the vapor pressure of grain neutral spirits.

The CO2 could potentially be flash-frozen into the solid state, kept aloft by Brownian motion, and then re-sublime in a vain attempt to reach equilibrium with the atmospheric CO2. Frosty breath.

Since this is CP, it is unlikely that alcohol would ever be in (1) a closed bottle or (2) allowed to evaporate from an open bottle. The actual situation is better addressed by biochemistry, of which I claim not expertise whatsoever, except, perhaps, with well peated single-malt Scotches

http://en.wikipedia.org/wiki/File:Carbon_dioxide_pressure-temperature_phase_diagram.svg[^]


"The difference between genius and stupidity is that genius has its limits." - Albert Einstein
"As far as we know, our computer has never had an undetected error." - Weisert
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GeneralRe: CO2 and Antarctica Pin
mikepwilson23-Dec-13 8:58
mikepwilson23-Dec-13 8:58 
GeneralRe: CO2 and Antarctica Pin
Erudite_Eric24-Dec-13 0:02
Erudite_Eric24-Dec-13 0:02 
GeneralRe: CO2 and Antarctica Pin
Ernst Iliov Stavro Blofeld24-Dec-13 6:15
Ernst Iliov Stavro Blofeld24-Dec-13 6:15 
GeneralAstronomy picture of the day: Tutulemma Pin
Gregory Gadow23-Dec-13 5:36
Gregory Gadow23-Dec-13 5:36 
GeneralRe: Astronomy picture of the day: Tutulemma Pin
Chris C-B23-Dec-13 6:01
Chris C-B23-Dec-13 6:01 
GeneralRe: Astronomy picture of the day: Tutulemma Pin
OriginalGriff23-Dec-13 6:08
mveOriginalGriff23-Dec-13 6:08 
GeneralRe: Astronomy picture of the day: Tutulemma Pin
glennPattonWork323-Dec-13 6:12
professionalglennPattonWork323-Dec-13 6:12 
GeneralRe: Astronomy picture of the day: Tutulemma Pin
kalberts23-Dec-13 8:08
kalberts23-Dec-13 8:08 
GeneralRe: Astronomy picture of the day: Tutulemma Pin
glennPattonWork324-Dec-13 12:11
professionalglennPattonWork324-Dec-13 12:11 
GeneralRe: Astronomy picture of the day: Tutulemma Pin
Kornfeld Eliyahu Peter23-Dec-13 6:58
professionalKornfeld Eliyahu Peter23-Dec-13 6:58 
GeneralMy boos irritating me... Pin
Kornfeld Eliyahu Peter23-Dec-13 4:47
professionalKornfeld Eliyahu Peter23-Dec-13 4:47 
GeneralRe: My boos irritating me... Pin
OriginalGriff23-Dec-13 4:48
mveOriginalGriff23-Dec-13 4:48 
GeneralRe: My boos irritating me... Pin
S Houghtelin23-Dec-13 4:52
professionalS Houghtelin23-Dec-13 4:52 
GeneralRe: My boos irritating me... Pin
Kornfeld Eliyahu Peter23-Dec-13 4:56
professionalKornfeld Eliyahu Peter23-Dec-13 4:56 
GeneralRe: My boos irritating me... Pin
S Houghtelin23-Dec-13 5:10
professionalS Houghtelin23-Dec-13 5:10 
GeneralRe: My boos irritating me... Pin
Kornfeld Eliyahu Peter23-Dec-13 6:53
professionalKornfeld Eliyahu Peter23-Dec-13 6:53 
GeneralRe: My boos irritating me... Pin
Gregory Gadow23-Dec-13 5:38
Gregory Gadow23-Dec-13 5:38 

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