try this
protected void btnSave_Click(object sender, EventArgs e)
{
DataTable dtNew = new DataTable("Employee Detils");
dtNew.Columns.Add(new DataColumn() { ColumnName = "EmpName", DataType = typeof(String) });
dtNew.Columns.Add(new DataColumn() { ColumnName = "EmpId", DataType = typeof(String) });
foreach (GridViewRow row in GridView1.Rows)
if (row.RowType == DataControlRowType.DataRow)
{
DataRow dr = dtNew.NewRow();
string empName = (row.FindControl("YourEmpNameControlId") as TextBox).Text;
string empId = (row.FindControl("YourEmpIdControlId") as TextBox).Text;
dr["EmpName"] = "Mr." + empName;
dr["EmpId"] = "+91" + empId;
dtNew.Rows.Add(dr);
}
GridView2.DataSource = dtNew;
GridView2.DataBind();
}