You're missing a close bracket:
INSERT INTO [empTable] ([empCode], [batch], [empMasterCode], [empName], [empFatherName], [empMotherName], [empVillage], [empParish], [empDeanery], [empDiocese], [empDOBirth], [empDOBaptism], [empQualification], [empBloodGroup], [empContact], [empBasicSalary], [empBrothers], [empSisters], [empAddress], [empDOJoining], [empPOJoining], [empPresentlyStationed], [empStatus], [empDOLeaving], [empDOSuspension], [empDODismissal], [empDORejoining], [empRemarks], [empPhoto] values(@empCode, @batch, @empMasterCode, @empName, @empFatherName, @empMotherName, @empVillage, @empParish, @empDeanery, @empDiocese, @empDOBirth, @empDOBaptism, @empQualification, @empBloodGroup, @empContact, @empBasicSalary, @empBrothers, @empSisters, @empAddress, @empDOJoining, @empPOJoining, @empPresentlyStationed, @empStatus, @empDOLeaving, @empDOSuspension, @empDODismissal, @empDORejoining, @empRemarks, @empPhoto)
If I rip out the content, it's more obvious:
INSERT INTO [empTable] ([empCode], ... [empRemarks], [empPhoto] values(@empCode, ... @empRemarks, @empPhoto)
Yo u need to close the list of columns with a ')':
Dim accmd As New OleDbCommand("INSERT INTO [empTable] ([empCode], [batch], [empMasterCode], [empName], [empFatherName], [empMotherName], [empVillage], [empParish], [empDeanery], [empDiocese], [empDOBirth], [empDOBaptism], [empQualification], [empBloodGroup], [empContact], [empBasicSalary], [empBrothers], [empSisters], [empAddress], [empDOJoining], [empPOJoining], [empPresentlyStationed], [empStatus], [empDOLeaving], [empDOSuspension], [empDODismissal], [empDORejoining], [empRemarks], [empPhoto]) values(@empCode, @batch, @empMasterCode, @empName, @empFatherName, @empMotherName, @empVillage, @empParish, @empDeanery, @empDiocese, @empDOBirth, @empDOBaptism, @empQualification, @empBloodGroup, @empContact, @empBasicSalary, @empBrothers, @empSisters, @empAddress, @empDOJoining, @empPOJoining, @empPresentlyStationed, @empStatus, @empDOLeaving, @empDOSuspension, @empDODismissal, @empDORejoining, @empRemarks, @empPhoto)", accon)