use this on textBox Keypress Event
here txtUID and txtPassword are two textBoxes .here it is checking if txtUID is not blank or say if it is Filled and then Pressing Enter the Focus Will move to txtPassword
Private Sub txtUID_KeyPress(ByVal sender As System.Object, ByVal e As System.Windows.Forms.KeyPressEventArgs) Handles txtUID.KeyPress
If Asc(e.KeyChar) = Keys.Enter Then
If txtUID.Text.Trim() <> "" Then
txtPassword.Focus()
End If
End If
End Sub
Implement this as Per your need.