Consuming Service through VB.Net 2010 that requires Soap Header security

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VB

I have a Visual Studio 2010 project that consumes a number of services using System.ServiceModel

These services have now been altered to include the following security in the soap headers:

<wsse:security xmlns:wsse="http://docs.oasis-open.org/wss/2004/01/oasis-200401-wss-wssecurity-secext-1.0.xsd">
           <wsse:usernametoken wsu:id="UsernameToken-14" xmlns:wsu="http://docs.oasis-open.org/wss/2004/01/oasis-200401-wss-wssecurity-utility-1.0.xsd">
             <wsse:username>username</wsse:username>
             <wsse:password type="http://docs.oasis-open.org/wss/2004/01/oasis-200401-wss-username-token-profile-1.0#PasswordText">passsword</wsse:password>
           </wsse:usernametoken>
         </wsse:security>

I have been able to get the application to work by adding the information into the web.config file, but I would prefer to programmatically add it to the relevant services through code.

Does anyone know how this can be done through code?