The error is pretty clear:
'Employeer.Service1' does not implement interface member 'Employeer.IService1.GetEmployee()'
Your Interface definition includes:
Employee GetEmployee();
but your class declares:
List<Employee> GetEmployee(int Employeerid) {...}
These are not the same overload: the Interface expects a method with no parameters that returns an Employee, you have only declared a method that takes an integer and returns a List of Employees.
Either change your interface definition, or your class, (or both) as is appropriate.