['Participants'] is not the correct way to write the table name.
Instead write like
[Participants] or only
Participants.
So, the query will look like...
SELECT
dbo.[Participants].[User Name],
dbo.Employee.Department
FROM
Employee, [Participants]
WHERE
Employee.[Display name] = [Participants].[User Name]
Or if you will use
INNER JOIN
, then query will be like...
SELECT
Part.[User Name],
emp.Department
FROM
Employee AS emp
INNER JOIN
[Participants] AS Part
ON
emp.[Display name] = Part.[User Name]
Thanks...