First of all why you using 103 format when you just want to cast in Datetime, you can directly cast the string into datetime
SELECT CONVERT(DATETIME,'2/25/2013 12:52:45 PM')
so if you want any formatted output than you can use 101, 103 etc...
SELECT CONVERT(VARCHAR,CONVERT(DATETIME,'2/25/2013 12:52:45 PM'),101) AS 'Format 101', CONVERT(VARCHAR,CONVERT(DATETIME,'2/25/2013 12:52:45 PM'),103) AS 'Format 103'
Result will be:
Format 101 | Format 103
02/25/2013 | 25/02/2013