Add a handler for 'Navigated' event:
private void webBrowser1_Navigated(object sender, WebBrowserNavigatedEventArgs e)
{
string query = e.Url.Query;
}
This will give you query string part of URL including the question mark at start.
Alternatively you can use:
webBrowser1.Document.Url.Query
but you'll have to make sure the browser finished loading the document.