The string version of a DataRow
is "System.Data.DataRow", because the system has no idea what the DataRow may contain, what part(s) of it you might want to display, or how you want them formatted.
If all you want is the row content as a concatenated string, then loop through the Row.Cells collection, and convert the content to individual strings, using a StringBuilder to "join" them together.
If you want to be cleverer, then use the DataTable as a DataSource for the ComboBox, and set the DisplayMember property to show only the column you are interested in:
Step by Step WPF Data Binding with Comboboxes[
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