HI, there are two methods to go with. one is using code behind and other is using jquery.
to show popup from code behind, use
CheckedChanged event of asp:chceckbox.
then simply (from code behind)
YourModalPopupExtender.Show();
by using jquery, do this
$('#myCheckBox').click (function ()
{
var thisCheck = $(this);
if (thischeck.is (':checked'))
{
$find('YourModalPopupExtender').show();
}
});