Learn MVC,WCF, step by step

Step 1. Go to www.google.com
Step 2. Type in "mvc tutorial" into the search box.
Step 3. Press the Enter key
Step 4. Click links with mouse for interesting articles.
Step 5. Read and follow tutorials.
Step 6. Repeat for WCF tutorials.

:)

Yes, there are people here who can help you, but you have to know:
Most important goal here is to learn and help learning.
You are supposed to try it on your own, and come here when you got stuck with something, with a concrete question about your code, design, etc.