IF you really want to list all COM port names and try to filter out which one(s) that are Android ports you can do something like this.
foreach (string portName in SerialPort.GetPortNames())
{
if (portName == someThing)
metroComboBox1.Items.Add(portName);
}
You have to fill in the code for the someThing.
You can also use
if (portName.StartsWith(someThing))
or
if (portName.EndsWith(someThing))
or
if (portName.Contains(someThing))
There are other ways to do it, but they are maybe a little bit too advanced.
In any case, you will have to know some key word or key data for your port to make this fool proof.
Do you really have that many COM ports on your computer?