Presumably, you are using a SerialPort to connect to the PIC, and this is working fine?
In which case, check the serial port data for the string or bytes that identifies a "give me the time" request from the PIC, and then send it the time in the appropriate format:
DateTime now = DateTime.Now;
string date = now.ToString("dd/MM/yy");
string time = now.ToString("HH:mm:ss");
serialPort.Write(date);